Dissertation Defense: Claudia Lau, Yale University, “Structural characterization of epitaxial oxide heterostructures via X-ray scattering”

Event time: 
Tuesday, March 10, 2020 - 2:30pm to 3:30pm
Dunham Laboratory (DL) See map
10 Hillhouse Avenue
New Haven, CT 06511
Event description: 

The impact of atomic-scale structural distortions on the transport properties of epitaxial thin film oxides and their interfaces is investigated through high resolution surface x-ray diffraction. The crystalline thin films studied are the metallic oxides (La,Sr)TiO3 and LaNiO3, the high mobility oxide BaSnO3, the high dielectric oxide LaInO3, and the ferroelectric oxide Pb(Zr,Ti)O3. Films were grown on SrTiO3 and DyScO3 commercial substrates by the physical vapor deposition techniques off-axis RF magnetron sputtering, pulsed laser deposition, and molecular beam epitaxy. High resolution x-ray diffraction measurements were taken at Argonne National Laboratory and Brookhaven National Laboratory, using synchrotron radiation from the Advanced Photon Source and the National Synchrotron Light Source II.
Crystal truncation rods are measured on epitaxial thin film (La,Sr)TiO3 and BaSnO3, both grown on SrTiO3 substrate and fully strained at thicknesses n≤10 unit cells. Three-dimensional electron density maps with picoscale resolution of the atomic positions are derived by the powerful phase retrieval method Coherent Bragg Rod Analysis. Supertetragonality, which is associated with interface-induced polarization, is observed in both films. The electron density map for the (La,Sr)TiO3 film additionally reveals polar displacements near both the film/substrate and film/vacuum interfaces. Deposition of a capping layer on the (La,Sr)TiO3 film suppresses polar displacement as well as lattice parameter expansion; the structural changes can be correlated to a measured enhancement in the material’s conductivity.
The energy-dependent resonant x-ray scattering technique is used to probe the cation stoichiometry of thicker, relaxed La-doped BaSnO3 films, which have a range of high room-temperature carrier mobilities. Analysis of energy scans measured around weakly scattering odd-order Bragg peaks reveal a less than 1% difference in stoichiometry between the films. In-plane φ rocking curves measured using a rotating copper anode laboratory x-ray source likewise show minimal differences in crystalline disorder. The φ rocking curve full width half maxima in contrast to those of the ω rocking curves suggest that film disorder is a reflection of mosaic size in the DyScO3 substrate.
Two epitaxial interfaces, the polar/nonpolar interface of LaInO3 with BaSnO3 and the ferroelectric/conducting interface of Pb(Zr,Ti)O3 with LaNiO3 are studied by a combination of crystal truncation rod and half-order Bragg peak analysis. Half-order Bragg peaks, the result of the perovskite unit cell doubling through rotations of oxygen octahedra, are isolated to the LaInO3 and LaNiO3 layers in these heterostructures. In the first system, mixed tilting and strong cation displacements remain robust, right up to the BaSnO3 interface for films as thin as three unit cells. Both the intrinsic polarization of the LaInO3 and the structural discontinuity across the LaInO3/BaSnO3 interface appear to contribute to the 10^4 enhancement in conductivity measured at the interface of the two oxides. In the second system, the ferroelectric functions as a gate with switchable polarization which modulates the conductivity of the LaNiO3 channel. As the applied voltage is swept through the coercive field of the ferroelectric, the oxygen octahedral rotations in the LaNiO3 exhibit a hysteresis loop, with larger rotations leading to reduced conductivity. The non-volatile switching and hysteresis behavior show promising potential for the future of all-oxide field effect devices.
Thesis Advisor: Charles Ahn